Professor, Chinese Academy of Sciences Academician
The website of group: http://www.scu.edu.cn/chem_asl
RESEARCH INTERESTS
asymmetric catalysis, the synthesis of bioactive compounds
We dedicated to develop new chiral catalysts and asymmetric catalytic systems. Based on the strategies of bifunctional catalysis and C2-symmetry, we designed and synthesized a new family of N,N'-dioxide amide compounds as chiral ligands and catalysts for the first time. Novel C2-symmetric N,N'-dioxides were readily prepared by the connection of two N-oxide amide subunits via a linker with variable conformation. The structural modify to fit the targeted enantioselective reactions could be easily established by using different chiral backbone, linker units, and amines with varied steric and electronic nature. In addition to acting as bifunctional organocatalysts, N,N'-dioxide amides were developed into useful neutral ligands for Lewis acidic metals, such as rare earth metals, alkaline earth metals, group IV metals, group XIII metals. Numerous chiral tetradentate ligand-metal complexes have been established as effective catalysts (see Acc. Chem. Rev. 2011, 44, 574; Acc. Chem. Res. 2017, 50, 2621; Chin. J. Chem. 2018, 36, 791; Acc. Chem. Res. 2022, 55, 415 for details). Additionally, we also developed a useful combined catalyst, and new bifunctional organocatalysts, such as guanidine-amide, bispidine-based diamine.
EDUCATION AND ACADEMIC CAREER
2000-present Professor, College of Chemistry, Sichuan University, Chengdu, China
1998-1999 Postdoctoral research, Colorado State University, USA
1997-2000 Professor, Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences (CAS), China
1988-1993 Assistant/associate professor, Southwest Normal University, Chongqing, China
1993-1996 Ph.D., Institute of Chemistry, CAS, China
1985-1988 M.Sc., Dept. of Chemistry, Lanzhou University, China
1981-1985 B.Sc., Dept. of Chemistry, Lanzhou University, China
HONORS AND AWARDS
2002 the National Science Fund for Distinguished Young Scholars (China)
2005 the Special Professor of the Chang Jiang Scholars by the Ministry of Education of China
2009 Higher Education Outstanding Scientific Research Output Awards (Science and Technology) from the Ministry of Education (First class, China)
2011 SciFinder Award for Creative Work in Synthetic Organic Chemistry, CCS
2012 the State Natural Science Award, P.R. China (Second class, China)
2013 a Chinese Academy of Sciences Academician
2014 a Fellow of the Royal Society of Chemistry
2016 Chiral Chemistry Award, CCS
2018 Physical Science Prize of Future Science Prize
2018 Huang Yaozeng Metal Organic Chemistry Award, CCS
2019 Higher Education Outstanding Scientific Research Output Awards (Science and Technology) from the Ministry of Education (First class, China)
2019 Ho Leung Ho Lee Foundation Prize for Scientific and Technological Progress
2019 Outstanding Talent Award of Sichuan
2020 the National Innovation and Competition Prize of China (Individual Medal)
2020 The Tan Kah Kee Science Awards
2020 Outstanding Teaching Award
2020 Science and Technology Outstanding Contribution Award of Sichuan
2021 the National Outstanding Professional and Technical Talents
2021 Chemistry Contribution Award of Chinese Chemical Society - China Petroleum and Chemical Corporation
EDITORIAL BOARDS
Editorial Board of Chemistry–An Asian Journal, Chinese Journal of Organic Chemistry, Chinese Journal of Inorganic Chemistry
Editorial Advisory Board of Angewandte Chemie, Advanced Synthesis & Catalysis, Current Organic Synthesis, Asian Journal of Organic Chemistry, Synlett/Synthesis, Chinese Chemical Letters, Chinese Journal of Structural Chemistry
SELECTED PUBLICATIONS
1. Dong Zhang,# Maoping Pu,# Zhenzhong Liu, Yuqiao Zhou, Zhendong Yang, Xiaohua Liu,* Yun-Dong Wu,* Xiaoming Feng,* Enantioselective anti-Dihalogenation of Electron-Deficient Olefin: A Triplet Halo-Radical Pylon Intermediate, J. Am. Chem. Soc. 2023, 145, 4808−4818.
2. Jinxiu Xu, Yanji Song, Jia Yang, Bingqian Yang, Zhishan Su, Lili Lin,* Xiaoming Feng,* Sterically Hindered and Deconjugative α-Regioselective Asymmetric Mannich Reaction of Meinwald Rearrangement-Intermediate, Angew. Chem. Int. Ed. 2023, 62, e202217887.
3. Tangyu Zhan, Liangkun Yang, Qiyou Chen, Rui Weng, Xiaohua Liu,* Xiaoming Feng,* Chiral Lewis Acid-Catalyzed Norrish Type II Cyclization to Synthesize α-Oxazolidinones via Enantioselective Protonation, CCS Chem. 2023, 5, accepted, DOI: 10.31635/ccschem.022.202202405.
4. Zhikun Wu,# Xiying Zhang,# Nian Xu, Xiaohua Liu,* Xiaoming Feng,* Asymmetric Catalytic Aerobic Oxidative Radical Addition/Hydroxylation/1,4-Aryl Migration Reaction of Olefins, ACS Catal. 2023, 13, 815−823.
5. Yuhao Mo, Qiyou Chen, Jinzhao Li, Dong Ye, Yuqiao Zhou, Shunxi Dong, Xiaohua Liu,* Xiaoming Feng,* Asymmetric Catalytic Conjugate Addition of Cyanide to Chromones and β‑Substituted Cyclohexenones, ACS Catal. 2023, 13, 877−886.
6. Shiyang Li, Cefei Zhang, Guihua Pan, Liangkun Yang, Zhishan Su, Xiaoming Feng, Xiaohua Liu,* Enantioselective Photochemical Carbene Insertion into C−C and C−H Bonds of 1,3-Diketones by a Guanidine-Amide Organocatalyst, ACS Catal. 2023, 13, 4656−4666.
7. Sijing Wang, Cefei Zhang, Da Li, Yuqiao Zhou, Zhishan Su, Xiaoming Feng, Shunxi Dong,* New Chiral N-Heterocyclic Olefin Bifunctional Organocatalysis in α-Functionalization of β-Ketoesters, Sci. China. Chem, 2023, 66, 147−154.
8. Yongyan Zhang, Jin Wu, Lichao Ning, Qianping Chen, Xiaoming Feng, Xiaohua Liu,* Enantioselective Synthesis of Tetrasubstituted Allenes via Addition/Arylation Tandem Reaction of 2-Activated 1,3-Enynes, Sci. China Chem. 2023, 66, 526−533.
9. Ziwei Zhong, Lichao Ning, Yican Lu, Jiuqi Tan, Lili Lin,* Xiaoming Feng,* Asymmetric Catalytic Alkylation of Vinyl Azides with 3-Bromo Oxindoles: Water-assisted Chemo- and Enantiocontrol, Sci. China Chem. 2023, 66, 799−807.
10. Lili Lin, Yuqiao Zhou, Weidi Cao, Shunxi Dong, Xiaohua Liu, Xiaoming Feng,* Progress in N,N′-Dioxide/metal Complex-catalyzed Asymmetric Reactions of Ylides, Sci. Sin. Chem. 2023, 53, 246−258.
11. Siyuan Wang, Yuqiao Zhou, Wanlong Xiao, Zegong Li, Xiaohua Liu,* Xiaoming Feng,* Asymmetric Synthesis of Complex Tricyclo[3.2.2.0] Nonenes from Racemic Norcaradienes: Kinetic Resolution via Diels–Alder Reaction, Chem. Sci. 2023, 14, 1844−1851.
12. Shiyu Wang, Chenhao Zhu, Lichao Ning, Dawei Li, Xiaoming Feng,* Shunxi Dong,* Regioselective C–H Alkylation of Anisoles with Olefins by Cationic Imidazolin-2-iminato Scandium(III) Alkyl Complexes, Chem. Sci., 2023, 14, 3132−3139.
13. Shunxi Dong, Xiaohua Liu,* Xiaoming Feng,* Asymmetric Catalytic Rearrangements with α‑Diazocarbonyl Compounds, Acc. Chem. Res. 2022, 55, 415−428.
14. Liuzhen Hou, Yuqiao Zhou, Han Yu, Tangyu Zhan, Weidi Cao,* Xiaoming Feng,* Enantioselective Radical Addition to Ketones through Lewis Acid-Enabled Photoredox Catalysis, J. Am. Chem. Soc. 2022, 144, 22140−22149.
15. Xiaobin Lin,# Maoping Pu,# Xinpeng Sang, Shiyang Li, Xiaohua Liu,* Yun-Dong Wu,* Xiaoming Feng,* Asymmetric Catalytic (2+1) Cycloaddition of Thioketones to Synthesize Tetrasubstituted Thiiranes, Angew. Chem. Int. Ed. 2022, 61, e202201151.
16. Qianchi Lin, Sujuan Zheng, Long Chen, Jin Wu, Jinzhao Li, Peizhi Liu, Shunxi Dong,* Xiaohua Liu, Qian Peng,* Xiaoming Feng,* Catalytic Regio- and Enantioselective Protonation for the Synthesis of Chiral Allenes: Synergistic Effect of the Counterion and Water, Angew. Chem. Int. Ed. 2022, 61, e202203650.
17. Hongkai Wang, Yang Xu, Fangqing Zhang, Yangbin Liu,* Xiaoming Feng,* Bimetallic Palladium/Cobalt Catalysis for Enantioselective Allylic C-H Alkylation via a Transient Chiral Nucleophile Strategy, Angew. Chem. Int. Ed. 2022, 61, e202115715.
18. Zhenda Tan, Shibo Zhu, Yangbin Liu,* Xiaoming Feng,* Photoinduced Chemo-, Site- and Stereoselective α-C(sp3)−H Functionalization of Sulfides, Angew. Chem. Int. Ed. 2022, 61, e202203374.
19. Wei Wang, Fangqing Zhang, Yangbin Liu,* Xiaoming Feng,* Diastereo- and Enantioselective Construction of Vicinal All-Carbon Quaternary Stereocenters via Iridium/Europium Bimetallic Catalysis, Angew. Chem. Int. Ed. 2022, 61, e202208837.
20. Wanlong Xiao, Lichao Ning, Shuang Xin, Shunxi Dong, Xiaohua Liu,* Xiaoming Feng,* Enantioselective [2+2] Cycloaddition of Allenyl Imidewith Mono-, or Disubstituted Alkenes, Angew. Chem. Int. Ed. 2022, 61, e202211596.
21. Lifeng Wang, Yuqiao Zhou, Zhishan Su, Fengcai Zhang, Weidi Cao, Xiaohua Liu,* Xiaoming Feng,* [3,3]-Sigmatropic Rearrangements of Naphthyl 1-Propargyl Ethers: para-Propargylation and Catalytic Asymmetric Dearomatization, Angew. Chem. Int. Ed. 2022, 61, e202211785.
22. Yang Xu, Hongkai Wang, Zhuang Yang, Yuqiao Zhou, Yangbin Liu,* Xiaoming Feng,* Stereodivergent Total Synthesis of Rocaglaol Initiated by Synergistic Dual-metal-catalyzed Asymmetric Allylation of Benzofuran-3(2H)-one, Chem, 2022, 8, 2011−2022.
23. Yun Liu, Yushuang Chen, Aying Yihuo, Yuqiao Zhou, Xiaohua Liu, Lili Lin,* Xiaoming Feng,* Diastereodivergent Synthesis of Chiral α‑Aminoketones via a Catalytic O−H Insertion/Barnes−Claisen Rearrangement Reaction, ACS Catal. 2022, 12, 1784−1790.
24. Han Yu, Tangyu Zhan, Yuqiao Zhou, Long Chen, Xiaohua Liu*, Xiaoming Feng,* Visible-Light-Activated Asymmetric Addition of Hydrocarbons to Pyridine-Based Ketones, ACS Catal. 2022, 12, 5136−5144.
25. Yao Luo, Qi Wei, Liangkun Yang, Yuqiao Zhou, Weidi Cao, Zhishan Su, Xiaohua Liu,* Xiaoming Feng,* Enantioselective Radical Hydroacylation of α,β-Unsaturated Carbonyl Compounds with Aldehydes by Triplet Excited Anthraquinone, ACS Catal. 2022, 12, 12984−12992.
26. Yan Wang, Aying Yihuo, Lifeng Wang, Shunxi Dong,* Xiaoming Feng,* Catalytic Asymmetric Synthesis of Chiral Azo Compounds via Interrupted Japp–Klingemann Reaction with Aryldiazonium Salts, Sci. China Chem. 2022, 65, 546−553.
27. Jiawen Lang, Siyuan Wang, Changli He, Xiaohua Liu,* Xiaoming Feng,* Asymmetric Synthesis of Isochromanone Derivatives via Trapping Carboxylic Oxonium Ylides and Aldol Cascade, Chem. Sci. 2022, 13, 1163−1168.
28. Fangqing Zhang, Bing-Tao Ren, Yuqiao Zhou, Yangbin Liu,* Xiaoming Feng,* Enantioselective Construction of cis-Hydroindole Scaffolds via an Asymmetric Inverse-Electron-Demand Diels–Alder reaction: Application to the Formal Total Synthesis of (+)-Minovincine, Chem. Sci. 2022, 13, 5562–5567.
29. Liangkun Yang, Wang-Yuren Li, Liuzhen Hou, Tangyu Zhan, Weidi Cao,* Xiaohua Liu, Xiaoming Feng,* NickelⅡ-Catalyzed Asymmetric Photoenolization/Mannich Reaction of (2-Alkylphenyl) Ketones, Chem. Sci. 2022, 13, 8576–8582.
30. Yi Li, Shuang Xin, Rui Weng, Xiaohua Liu,* Xiaoming Feng,* Asymmetric Synthesis of Chromanone Lactones via Vinylogous Conjugate Addition of Butenolide to 2-Ester Chromones, Chem. Sci. 2022, 13, 8871–8875.
31. Yangbin Liu, Xiaohua Liu, Xiaoming Feng,* Recent Advances in Metal-catalysed Asymmetric Sigmatropic Rearrangements, Chem. Sci. 2022, 13, 12290−12308.
32. Fei Tan,# Maoping Pu,# Jun He, Jinzhao Li, Jian Yang, Shunxi Dong, Xiaohua Liu,* Yun-Dong Wu,* Xiaoming Feng,* Catalytic Asymmetric Homologation of Ketones with α-Alkyl-α-diazoesters, J. Am. Chem. Soc. 2021, 143, 2394−2402.
33. Wei Yang,# Maoping Pu,# Xiaobin Lin, Min Chen, Yanji Song, Xiaohua Liu,* Yun-Dong Wu,* Xiaoming Feng,* Enantioselective Formal Vinylogous N−H Insertion of Secondary Aliphatic Amines Catalyzed by a High-Spin Cobalt(II) Complex, J. Am. Chem. Soc. 2021, 143, 9648−9656.
34. Wen Liu,# Maoping Pu,# Jun He, Tinghui Zhang, Shunxi Dong, Xiaohua Liu,* Yun-Dong Wu,* Xiaoming Feng,* Iron-Catalyzed Enantioselective Radical Carboazidation and Diazidation of a,b-Unsaturated Carbonyl Compounds, J. Am. Chem. Soc. 2021, 143, 11856−11863.
35. Long Chen,# Maoping Pu,# Shiyang Li, Xinpeng Sang, Xiaohua Liu,* Yun-Dong Wu,* and Xiaoming Feng,* Enantioselective Synthesis of Nitriles Containing a Quaternary Carbon Center by Michael Reactions of Silyl Ketene Imines with 1‑Acrylpyrazoles, J. Am. Chem. Soc. 2021, 143, 19091–19098.
36. Yong Xia, Xiaohua Liu,* Xiaoming Feng,* Asymmetric Catalytic Reactions of Donor-Acceptor Cyclopropanes, Angew. Chem. Int. Ed. 2021, 60, 9192–9204.
37. Jinxiu Xu, Yanji Song, Jun He, Shunxi Dong, Lili Lin, Xiaoming Feng,* Asymmetric Catalytic Vinylogous Addition Reactions Initiated by Meinwald Rearrangement of Vinyl Epoxides, Angew. Chem. Int. Ed. 2021, 60, 14521–14527.
38. Li Dai, Wen Liu, Yuqiao Zhou, Zi Zeng, Xinyue Hu, Weidi Cao,* Xiaoming Feng,* Catalytic Asymmetric Halogenation/Semipinacol Rearrangement of 3-Hydroxyl-3-vinyl Oxindoles: A Stereodivergent Kinetic Resolution Process, Angew. Chem. Int. Ed. 2021, 60, 26599–26603.
39. Xinyue Hu, Xiaoxue Tang, Xiying Zhang, LiLi Lin,* Xiaoming Feng,* Catalytic Asymmetric Nakamura Reaction by Gold(I)/chiral N,Nʹ-dioxide-indium(III) or Nickel(II) Synergistic Catalysis, Nat. Commun. 2021, 12, 3012–3021.
40. Guihua Pan, Changli He, Min Chen, Qian Xiong, Weidi Cao,* Xiaoming Feng,* Synthesis of Dihydroisoquinoline and Dihydropyridine Derivatives via Asymmetric Dearomative Three-component Reaction, CCS Chem. 2021, 3, 2012−2020.
41. Wanlong Xiao, Yuhao Mo, Jing Guo, Zhishan Su, Shunxi Dong,* Xiaoming Feng,* Catalytic Enantioselective Synthesis of Macrodiolides and Their Application in Chiral Recognition, Chem. Sci. 2021, 12, 2940−2947.
42. Xia Zhong, Ziwei Zhong, Zhikun Wu, Zhen Ye, Yuxiang Feng, Shunxi Dong, Xiaohua Liu,* Qian Peng,* Xiaoming Feng,* Chiral Lewis Acid-bonded Picolinaldehyde Enables Enantiodivergent Carbonyl Catalysis in Mannich/Condensation Reaction of Glycine Ester, Chem. Sci. 2021, 12, 4353–4360.
43. Chaoran Xu, Jianglin Qiao, Shunxi Dong,* Yuqiao Zhou, Xiaohua Liu, Xiaoming Feng,* Asymmetric Synthesis of Dihydro-1,3-dioxepines by Rh(II)/Sm(III) Relay Catalytic Three-component Tandem [4+3]-Cycloaddition, Chem. Sci. 2021, 12, 5458–5463.
44. Mingming Guan, Shiyu Wang, Yao Luo, Weidi Cao,* Xiaohua Liu, Xiaoming Feng,* Catalytic Asymmetric Addition of Thiols to Silyl Glyoxylates for Synthesis of Multi-hetero-atom Substituted Carbon Stereocenter, Chem. Sci. 2021, 12, 7498−7503.
45. Xia Zhong, Jiuqi Tan, Jianglin Qiao, Yuqiao Zhou, Cidan Lv, Zhishan Su, Shunxi Dong,* Xiaoming Feng,* Asymmetric Catalytic Synthesis of Spirocyclobutyl Oxindoles and Beyond via [2+2] Cycloaddition and Sequential Transformations, Chem. Sci. 2021, 12, 9991−9997.
46. Dong Zhang, Zhisan Su, Qianwen He, Zhikun Wu, Yuqiao Zhou, Chenjing Pan, Xiaohua Liu,* Xiaoming Feng,* Diversified Transformations of Tetrahydroindolizines to Construct Chiral 3-Arylindolizines and Dicarbofunctionalized 1,5-Diketones, J. Am. Chem. Soc. 2020, 142, 15975−15985.
47. Xiying Zhang, Wangbin Wu, Weidi Cao, Han Yu, Xi Xu, Xiaohua Liu,* Xiaoming Feng,* Enantioselective Radical-Polar Crossover Reactions of Indanonecarboxamides with Alkenes, Angew. Chem. Int. Ed. 2020, 59, 4846−4850.
48. Yushuang Chen, Yun Liu, Zhaojing Li, Shunxi Dong,* Xiaohua Liu, Xiaoming Feng,* Tandem Insertion/[1,3]-Rearrangement: Highly Enantioselective Construction of a-Aminoketones, Angew. Chem. Int. Ed. 2020, 59, 8052−8056.
49. Tengfei Kang, Liuzhen Hou, Sai Ruan, Weidi Cao, Xiaohua Liu,* Xiaoming Feng,* Lewis acid-catalyzed asymmetric reactions of β,γ-unsaturated 2-acyl imidazoles, Nat. Commun. 2020, 11, 3869.
50. Xiaobin Lin, Zheng Tan, Wenkun Yang, Wei Yang, Xiaohua Liu,* Xiaoming Feng,* Chiral Cobalt(ΙΙ) Complex Catalyzed Asymmetric [2,3]-Sigmatropic Rearrangement of Allylic Selenides with α-Diazo Pyrazoleamides, CCS Chem. 2020, 2, 1423–1433.
51. Jian Xu, Ziwei Zhong, Mingyi Jiang, Yuqiao Zhou, Xiaohua Liu,* Xiaoming Feng,* Asymmetric Catalytic Concise Synthesis of Hetero-3,3ʹ-Bisoxindoles for the Construction of Bispyrroloindoline Alkaloids, CCS Chem. 2020, 2, 1894–1902.
52. Zhen Wang, Xiaohua Liu,* Xiaoming Feng,* Asymmetric Catalysis Enabled by Chiral N,N'-Dioxide–Nickel(II) Complexes, Aldrichimica ACTA, 2020, 53, 3−10.
53. Qianchi Lin, Bowen Hu, Xi Xu, Shunxi Dong, Xiaohua Liu,* Xiaoming Feng,* Chiral N,Nʹ-Dioxide/Mg(OTf)2 Complex-Catalyzed Asymmetric [2,3]-Rearrangement of in situ Generated Ammonium Salts, Chem. Sci. 2020, 11, 3068−3073.
54. Bin Shen, Qianwen He, Shunxi Dong, Xiaohua Liu,* Xiaoming Feng,* Chiral Cobalt(II) Complex Catalyzed Enantioselective Aza-Piancatelli Rearrangement/Diels-Alder Cascade Reaction, Chem. Sci. 2020, 11, 3862−3867.
55. Lifeng Wang, Pengfei Zhou, Qianchi Lin, Shunxi Dong, Xiaohua Liu,* Xiaoming Feng,* Chiral Fe(II) Complex Catalyzed Enantioselective [1,3] O-to-C Rearrangement of Alkyl Vinyl Ethers and Synthesis of Chromanols and Beyond, Chem. Sci. 2020, 11, 10101-10106.
56. Ziwei Zhong, Zhijie Xiao, Xiaohua Liu, Weidi Cao,* Xiaoming Feng,* Catalytic Asymmetric Synthesis of 3,2'-Pyrrolinyl Spirooxindoles via Conjugate Addition/Schmidt-type Rearrangement of Vinyl Azides and (E)-Alkenyloxindoles, Chem. Sci. 2020, 11, 11492-11497.
57. Bin Shen, Qianwen He, Shunxi Dong, Xiaohua Liu,* Xiaoming Feng,* Chiral Cobalt(II) Complex Catalyzed Enantioselective Aza-Piancatelli Rearrangement/Diels-Alder Cascade Reaction, Chem. Sci. 2020, 11, 3862−3867.
58. Weidi Cao, Xiaohua Liu, Xiaoming Feng,* Chiral N,Nʹ-dioxide and Their Metal Complexes in Asymmetric Catalysis (in Chinese), Chin. Sci. Bull. 2020, 65, 2941−2951.
59. Qian Xiong, Shunxi Dong, Yushuang Chen, Xiaohua Liu,* Xiaoming Feng,* Asymmetric Synthesis of Tetrazole and Dihydroisoquinoline Derivatives by Isocyanidebased Multicomponent Reactions, Nat. Commun. 2019, 10, 2116.
60. Tengfei Kang, Weidi Cao, Liuzhen Hou, Qiong Tang, Sijia Zou, Xiaohua Liu, Xiaoming Feng,* Chiral Zinc(II)-Catalyzed Enantioselective Tandem a-Alkenyl Addition/Proton Shift Reaction of Silyl Enol Ethers with Ketimines, Angew. Chem. Int. Ed. 2019, 58, 2464–2468.
61. Shulin Ge, Weidi Cao, Tengfei Kang, Bowen Hu, Hang Zhang, Zhishan Su, Xiaohua Liu, Xiaoming Feng,* Bimetallic Catalytic Asymmetric Tandem Reaction of β-Alkynyl Ketones to Synthesize 6,6-Spiroketals, Angew. Chem. Int. Ed. 2019, 58, 4017–4021.
62. Haifeng Zheng, Yan Wang, Chaoran Xu, Qian Xiong, Lili Lin, Xiaoming Feng,* Diversified 1,6-Enynes Cycloisomerization/Diels-Alder Reactions via Bimetallic Relay Asymmetric Catalysis, Angew. Chem. Int. Ed. 2019, 58, 5327–5331.
63. Qiong Tang, Kai Fu, Peiran Ruan, Shunxi Dong,* Zhishan Su, Xiaohua Liu, Xiaoming Feng,* Asymmetric Catalytic Formal 1,4-Allylation of b,g-Unsaturated a-Ketoesters: Allylboration/Oxy-Cope Rearrangement, Angew. Chem. Int. Ed. 2019, 58, 11846–11851.
64. Xiaobin Lin, Wei Yang, Wenkun Yang, Xiaohua Liu,* and Xiaoming Feng,* Asymmetric Catalytic [2,3] Stevens and Sommelet–Hauser Rearrangements of a-Diazo Pyrazoleamides with Sulfides, Angew. Chem. Int. Ed. 2019, 58, 13492–13498.
65. Chaoran Xu, Kaixuan Wang, Dawei Li, Lili Lin,* and Xiaoming Feng,* Asymmetric Synthesis of Oxa-Bridged Oxazocines by Rh(II)/Zn(II) Relay Catalytic [4+3] Cycloaddition Reaction, Angew. Chem. Int. Ed. 2019, 58, 18438–18442.
66. Yu Zhang, Fengcai Zhang, Long Chen, Jian Xu, Xiaohua Liu,* Xiaoming Feng,* Asymmetric Synthesis of P-Stereogenic Compounds via Thulium(III)-Catalyzed Desymmetrization of Dialkynylphosphine Oxides, ACS Catal. 2019, 9, 4834−4840.
67. Wangbin Wu, Weidi Cao, Linfeng Hu, Zhishan Su, Xiaohua Liu,* and Xiaoming Feng,* Asymmetric Baeyer–Villiger Oxidation: Classical and Parallel Kinetic Resolution of 3-Substituted Cyclohexanones and Desymmetrization of meso-Disubstituted Cycloketones, Chem. Sci. 2019, 10, 7003−7008.
68. Ke Zheng, Xiaohua Liu, Xiaoming Feng,* Recent Advances in Metal-Catalyzed Asymmetric 1,4-Conjugate Addition (ACA) of Nonorganometallic Nucleophiles, Chem. Rev. 2018, 118, 7586–7656.
69. Xiaobin Lin, Yu Tang, Wei Yang, Fei Tan, Lili Lin, Xiaohua Liu,* Xiaoming Feng,* Chiral Nickel(II) Complex Catalyzed Enantioselective Doyle-Kirmse Reaction of α-Diazo Pyrazoleamides, J. Am. Chem. Soc. 2018, 140, 3299–3305.
70. Haifeng Zheng, Yan Wang, Chaoran Xu, Xi Xu, Lili Lin, Xiaohua Liu,* Xiaoming Feng,* Stereodivergent Synthesis of Vicinal Quaternary-quaternary Stereocenters and Bioactive Hyperolactones, Nat. Commun. 2018, 1968−1974.
71. Xi Xu, Jianlin Zhang, Shunxi Dong, Lili Lin, Xiaobin Lin, Xiaohua Liu, Xiaoming Feng,* Nickel(II)-Catalyzed Asymmetric Propargyl [2,3] Wittig Rearrangement of Oxindole Derivatives: A Chiral Amplification Effect, Angew. Chem. Int. Ed. 2018, 57, 8734–8738.
72. Yuhang Zhou, Lili Lin, Xiaohua Liu,* Xinyue Hu, Yan Lu, Xiying Zhang, Xiaoming Feng,* Catalytic Asymmetric Diels-Alder Reaction/[3,3] Sigmatropic Rearrangement Cascade of 1-Thiocyanatobutadienes, Angew. Chem. Int. Ed. 2018, 57, 9113–9116.
73. Dong Zhang, Lili Lin, Jian Yang, Xiaohua Liu, Xiaoming Feng,* Asymmetric Synthesis of Tetrahydroindolizines by Bimetallic Relay Catalyzed Cycloaddition of Pyridinium Ylides, Angew. Chem. Int. Ed. 2018, 57, 12323–12327.
74. Fei Tan, Xiaohua Liu,* Yan Wang, Shunxi Dong, Han Yu, Xiaoming Feng,* Chiral Lewis Acid Catalyzed Reactions of a-Diazoester Derivatives: Construction of Dimeric Polycyclic Compounds, Angew. Chem. Int. Ed. 2018, 57, 16176–16179.
75. Yushuang Chen, Shunxi Dong, Xi Xu, Xiaohua Liu, Xiaoming Feng,* Bimetallic Rhodium(II)/Indium(III) Relay Catalysis for Tandem Insertion/Asymmetric Claisen Rearrangement, Angew. Chem. Int. Ed. 2018, 57, 16554–16558.
76. Xiaohua Liu, Xiaoming Feng,* Dual Nickel and Br➢nsted Acid Catalysis for Hydroalkenylation, Angew. Chem. Int. Ed. 2018, 57, 16604–16605
77. Yali Xu, Fenzhen Chang, Weidi Cao, Xiaohua Liu, Xiaoming Feng,* Catalytic Asymmetric Chemodivergent C2 Alkylation and [3 + 2]-Cycloaddition of 3‑Methylindoles with Aziridines, ACS Catal. 2018, 8, 10261–10266.
78. Yulong Kuang, Bin Shen, Li Dai, Qian Yao, Xiaohua Liu,* Lili Lin, Xiaoming Feng,* Diastereodivergent Asymmetric Michael-Alkylationreactions Using Chiral N,N′-Dioxide/Metal Complexes, Chem. Sci. 2018, 9, 688–692.
79. Xiaohua Liu, Shunxi Dong, Lili Lin, Xiaoming Feng,* Chiral Amino Acids-Derived Catalysts and Ligands, Chin. J. Chem. 2018, 36, 791–797.
80. Xiaohua Liu, Haifeng Zheng, Yong Xia, Lili Lin, Xiaoming Feng,* Asymmetric Cycloaddition and Cyclization Reactions Catalyzed by Chiral N,N′‑Dioxide-Metal Complexes, Acc. Chem. Res. 2017, 50, 2621-2631.
81. Pengfei Zhou, Lili Lin, Long Chen, Xia Zhong, Xiaohua Liu, Xiaoming Feng,* Iron-Catalyzed Asymmetric Haloazidation of α,β-Unsaturated Ketones: Construction of Organic Azides with Two Vicinal Stereocenters, J. Am. Chem. Soc. 2017, 139, 13414-13419.
82. Jianfeng Zheng, Lili Lin, Li Dai, Qiong Tang, Xiaohua Liu,* Xiaoming Feng,* Nickel-Catalyzed Conjugate Addition of Silyl Ketene Imines to In Situ Generated Indol-2-ones: Highly Enantioselective Construction of Vicinal All-Carbon Quaternary Stereocenters, Angew. Chem. Int. Ed. 2017, 56, 13107-13111.
83. Jun Li, Lili Lin, Bowen Hu, Pengfei Zhou, Tianyu Huang, Xiaohua Liu,* Xiaoming Feng,* Gold(I)/Chiral N,N’-Dioxide–Nickel(II) Relay Catalysis for Asymmetric Tandem Intermolecular Hydroalkoxylation/Claisen Rearrangement, Angew. Chem. Int. Ed. 2017, 56, 885-888.
84. Tianyu Huang, Xiaohua Liu,* Jiawen Lang, Jian Xu, Lili Lin, Xiaoming Feng,* Asymmetric Aerobic Oxidative Cross-Coupling of Tetrahydroisoquinolines with Alkynes, ACS Catal. 2017, 7, 5654-5660.
85. Jie Ji, Lili Lin, Qiong Tang, Tengfei Kang, Xiaohua Liu, Xiaoming Feng,* Highly Efficient Asymmetric Synthesis of Chiral γ‑Alkenyl Butenolides Catalyzed by Chiral N,N′‑Dioxide-Scandium(III) Complexes, ACS Catal. 2017, 7, 3763-3767.
86. Yuting Liao, Baixin Zhou, Yong Xia, Xiaohua Liu,* Lili Lin, Xiaoming Feng,* Asymmetric [3 + 2] Cycloaddition of 2,2′-Diester Aziridines To Synthesize Pyrrolidine Derivatives, ACS Catal. 2017, 7, 3934-3939.
87. Xiangjin Lian, Lili Lin, Kai Fu, Baiwei Ma, Xiaohua Liu, Xiaoming Feng,* A new approach to the asymmetric Mannich reaction catalyzed by chiral N,N’-dioxide-metal complexes, Chem. Sci., 2017, 8, 1238-1242.
88. Yu Zhang, Yuting Liao, Xiaohua Liu,* Xi Xu, Lili Lin, Xiaoming Feng,* Catalytic asymmetric hydroxylative dearomatization of 2-naphthols: synthesis of lacinilene derivatives, Chem. Sci. 2017, 8, 6645-6649.
89. Yong Xia, Lili Lin, Fenzhen Chang, Yuting Liao, Xiaohua Liu,* and Xiaoming Feng,* Asymmetric Ring Opening/Cyclization/Retro-Mannich Reaction of Cyclopropyl Ketones with Aryl 1,2-Diamines for the Synthesis of Benzimidazole Derivatives, Angew. Chem. Int. Ed. 2016, 55, 12228-12232.
90. Haipeng Hu, Yangbin Liu, Lili Lin, Yuheng Zhang, Xiaohua Liu,* and Xiaoming Feng,* Kinetic Resolution of 2H-Azirines by Asymmetric Imine Amidation, Angew. Chem. Int. Ed. 2016, 55, 10098-10101.
91. Qian Yao, Yuting Liao, Lili Lin, Xiaobin Lin, Jie Ji, Xiaohua Liu,* and Xiaoming Feng,* Efficient Synthesis of Chiral Trisubstituted 1,2-Allenyl Ketones by Catalytic Asymmetric Conjugate Addition of Malonic Esters to Enynes, Angew. Chem. Int. Ed. 2016, 55, 1859-1863.
92. Yangbin Liu, Xiaohua Liu,* Haipeng Hu, Jing Guo, Yong Xia, Lili Lin, and Xiaoming Feng,* Synergistic Kinetic Resolution and Asymmetric Propargyl Claisen Rearrangement for the Synthesis of Chiral Allenes, Angew. Chem. Int. Ed. 2016, 55, 4054-4058.
93. Tengfei Kang, Shulin Ge, Lili Lin, Yan Lu, Xiaohua Liu,* and Xiaoming Feng,* A Chiral N,N′-Dioxide–ZnII Complex Catalyzes the Enantioselective [2+2] Cycloaddition of Alkynones with Cyclic Enol Silyl Ethers, Angew. Chem. Int. Ed. 2016, 55, 5541-5544.
94. Jun Li, Lili Lin, Bowen Hu, Xiangjin Lian, Gang Wang, Xiaohua Liu,* and Xiaoming Feng,* Bimetallic Gold(I)/Chiral N,N′-Dioxide Nickel(II) Asymmetric Relay Catalysis: Chemo- and Enantioselective Synthesis of Spiroketals and Spiroaminals, Angew. Chem. Int. Ed. 2016, 55, 6075-6078.
95. Pengfei Zhou, Yunfei Cai, Xia Zhong, Weiwei Luo, Tengfei Kang, Jun Li, Xiaohua Liu,* Lili Lin, and Xiaoming Feng,* Catalytic Asymmetric Intra- and Intermolecular Haloetherification of Enones: An Efficient Approach to (-)-Centrolobine, ACS Catal. 2016, 6, 7778-7783.
96. Gang Wang, Xiaohua Liu,*, Yushuang Chen, Jian Yang, Jun Li, Lili Lin, and Xiaoming Feng,* Diastereoselective and Enantioselective Alleno-aldol Reaction of Allenoates with Isatins to Synthesis of Carbinol Allenoates Catalyzed by Gold, ACS Catal. 2016, 6, 2482-2486.
97. Yali Xu, Yuting Liao, Lili Lin, Yuhang Zhou, Jun Li, Xiaohua Liu, and Xiaoming Feng,* Catalytic Asymmetric Inverse-Electron Demand 1,3-Dipolar Cycloaddition of Isoquinolinium Methylides with Enecarbamates by a Chiral N,N′-Dioxide/Ag(I) Complex, ACS Catal. 2016, 6, 589-592.
98. Jing Guo, Yangbin Liu, Xiangqiang Li, Xiaohua Liu,* Lili Lin and Xiaoming Feng,* Nickel(II)-catalyzed enantioselective cyclopropanation of 3-alkenyl-oxindoles with phenyliodonium ylide via free carbine, Chem. Sci. 2016, 7, 2717-2721.
99. Yuting Liao, Xiaohua Liu,* Yu Zhang, Yali Xu, Yong Xia, Lili Lin and Xiaoming Feng,* Asymmetric [3 + 2] cycloaddition of donor–acceptor aziridines with aldehydes via carbon–carbon bond cleavage, Chem. Sci. 2016, 7, 3775-3779.
100. Weiwei Luo, Xiao Yuan, Lili Lin, Pengfei Zhou, Xiaohua Liu* and Xiaoming Feng,* A N,N′-dioxide/Mg(OTf)2 complex catalyzed enantioselective a-addition of isocyanides to alkylidene malonates, Chem. Sci. 2016, 7, 4736-4740.
101. Yong Xia, Xiaohua Liu*, Haifeng Zheng, Lili Lin, Xiaoming Feng,* A symmetric Synthesis of 2,3-Dihydropyrroles by Ring-Opening/Cyclization of Cyclopropyl Ketones Using Primary Amines, Angew. Chem. Int. Ed. 2015, 54, 227-230.
102. Yong Xia, Lili Lin, Fenzhen Chang, Xuan Fu, Xiaohua Liu*, Xiaoming Feng,* Asymmetric Ring-Opening of Cyclopropyl Ketones with Thiol, Alcohol, and Carboxylic Acid Nucleophiles Catalyzed by a Chiral N,N′-Dioxide–Scandium(III) Complex, Angew. Chem. Int. Ed. 2015, 54, 13748-13752.
103. Haifeng Zheng, Xiaohua Liu*, Chaoran Xu, Yong Xia, Lili Lin, Xiaoming Feng,* Regio- and Enantioselective Aza-Diels–Alder Reactions of 3-Vinylindoles: A Concise Synthesis of the Antimalarial Spiroindolone NITD609, Angew.Chem.Int. Ed. 2015, 54, 10958-10962.
104. Jiannan Zhao, Bing Fang, Weiwei Luo, Xiaoyu Hao, Xiaohua Liu, Lili Lin, Xiaoming Feng,* Enantioselective Construction of Vicinal Tetrasubstituted Stereocenters by the Mannich Reaction of Silyl Ketene Imines with Isatin-Derived Ketimines, Angew. Chem. Int. Ed. 2015, 54, 241-244.
105. Wei Li, Fei Tan, Xiaoyu Hao, Gang Wang, Yu Tang, Xiaohua Liu, Lili Lin, Xiaoming Feng,* Catalytic Asymmetric Intramolecular Homologation of Ketones with α-Diazoesters: Synthesis of Cyclic α-Aryl/Alkyl β-Ketoesters, Angew. Chem. Int. Ed. 2015, 54, 1608-1611.
106. Xiaohu Zhao, Xiaohua Liu*, Hongjiang Mei, Jing Guo, Lili Lin, Xiaoming Feng,* Asymmetric Dearomatization of Indoles through a Michael/Friedel-Crafts-Type Cascade To Construct Polycyclic Spiroindolines, Angew. Chem. Int. Ed. 2015, 54, 4032-4035.
107. Yin Zhu, Xiaohua Liu,* Shunxi Dong, Yuhang Zhou, Wei Li, Lili Lin, Xiaoming Feng,* Asymmetric NH Insertion of Secondary and Primary Anilines under the Catalysis of Palladium and Chiral Guanidine Derivatives, Angew. Chem. Int. Ed. 2014, 53, 1636-1640.
108. Yangbin Liu, Haipeng Hu, Haifeng Zheng, Yong Xia, Xiaohua Liu, Lili Lin, Xiaoming Feng,* Nickel(II)-Catalyzed Asymmetric Propargyl and Allyl Claisen Rearrangements to Allenyl- and Allyl-Substituted β-Ketoesters, Angew. Chem. Int. Ed. 2014, 53, 11579-11582.
109. Xiaohua Liu, Lili Lin and Xiaoming Feng,* Chiral N,N′-Dioxide Ligands: Synthesis, Coordination Chemistry and Asymmetric Catalysis, Org. Chem. Front., 2014, 1, 298-302.
110. Shunxi Dong, Xiaohua Liu*, Yin Zhu, Peng He, Lili Lin, Xiaoming Feng,* Organocatalytic Oxyamination of Azlactones: Kinetic Resolution of Oxaziridines and Asymmetric Synthesis of Oxazolin-4-ones, J. Am. Chem. Soc. 2013, 135, 10026-10029.
111. Jiannan Zhao, Xiaohua Liu, Weiwei Luo, Mingsheng Xie, Lili Lin, Xiaoming Feng,* Asymmetric Synthesis of β-Amino Nitriles through a ScIII-Catalyzed Three-Component Mannich Reaction of Silyl Ketene Imines, Angew. Chem. Int. Ed. 2013, 52, 3473-3477.
112. Mingsheng Xie, Xiaohua Liu, Xiaoxia Wu, Yunfei Cai, Lili Lin, Xiaoming Feng,* Catalytic Asymmetric [8+2] Cycloaddition: Synthesis of Cycloheptatriene-Fused Pyrrole Derivative, Angew. Chem. Int. Ed. 2013, 52, 5604-5607.
113. Jing Guo, Shunxi Dong, Yulong Zhang, Yulong Kuang, Xiaohua Liu, Lili Lin, Xiaoming Feng,* Chiral Scandium(III)-Catalyzed Enantioselective α-Arylation of N-Unprotected 3-Substituted Oxindoles with Diaryliodonium Salts, Angew. Chem. Int. Ed. 2013, 52, 10245-10249.
114. Wei Li, Xiaohua Liu, Fei Tan, Xiaoyu Hao, Jianfeng Zheng, Lili Lin, Xiaoming Feng,* Catalytic Homologation of α-Ketoesters with α-Diazoesters: Enantioselective Synthesis of Succinate Derivatives with Chiral Quaternary Centers, Angew. Chem. Int. Ed. 2013, 52, 10883-10886.
115. Ke Zheng, Xiaohua Liu, Song Qin, Mingsheng Xie, Lili Lin, Changwei Hu, Xiaoming Feng,* Completely OH-Selective FeCl3-Catalyzed Prins Cyclization: Highly Stereoselective Synthesis of 4-OH-Tetrahydropyrans, J. Am. Chem. Soc. 2012, 134, 17564-17573.
116. Lin Zhou, Xiaohua Liu, Jie Ji, Yuheng Zhang, Lili Lin, Xiaoming Feng,* Enantioselective Baeyer−Villiger Oxidation: Desymmetrization of Meso Cyclic Ketones and Kinetic Resolution of Racemic 2‑Arylcyclohexanones, J. Am. Chem. Soc. 2012, 134, 17023-17026.
117. Wei Li, Xiaohua Liu, Xiaoyu Hao, Yunfei Cai, Lili Lin, Xiaoming Feng,* A Catalytic Asymmetric Ring-Expansion Reaction of Isatins and α-Alkyl-α-Diazoesters: Highly Efficient Synthesis of Functionalized 2-Quinolone Derivatives, Angew. Chem. Int. Ed. 2012, 51, 8644-8647.
118. Zhen Wang, Zhenling Chen, Sha Bai, Wei Li, Xiaohua Liu, Lili Lin, Xiaoming Feng,* Highly Z-Selective Asymmetric Conjugate Addition of Alkynones with Pyrazol-5-ones Promoted by N,N′-Dioxide–Metal Complexes, Angew. Chem. Int. Ed. 2012, 51, 2776-2779.
119. Ke Shen, Xiaohua Liu, Lili Lin, Xiaoming Feng,* Recent Progress in Enantioselective Synthesis of C3-functionalized Oxindoles: Rare Earth Metals Take Action, Chem. Sci. 2012, 3, 327-334.
120. Yangyang Chu, Xiaohua Liu, Wei Li, Xiaolei Hu, Lili Lin and Xiaoming Feng,* Asymmetric Catalytic Epoxidation of α,β-Unsaturated Carbonyl Compounds with Hydrogen Peroxide: Additive-free and Wide Substrate Scope, Chem. Sci. 2012, 3, 1996-2000.
121. Ke Zheng, Lili Lin, Xiaoming Feng,* Chiral N,N′-Dioxide-Ni(II) Complex Catalyzed Asymmetric Carbonyl-Ene Reaction Of Ethyl Trifluoropyruvate, Acta Chim. Sinica 2012, 70, 1785-1790.
122. Xiaohua Liu, Lili Lin, Xiaoming Feng,* Chiral N,N′-Dioxides: New Ligands and Organocatalysts for Catalytic Asymmetric Reactions, Acc. Chem. Res. 2011, 44, 574-587.
123. Jun Wang, Xiaohua Liu, Xiaoming Feng,* Asymmetric Strecker Reactions, Chem. Rev. 2011, 111, 6947-6983.
124. Wei Li, Xiaohua Liu, Xiaoyu Hao, Xiaolei Hu, Yangyang Chu, Weidi Cao, Song Qin, Changwei Hu, Lili Lin, Xiaoming Feng,* New Electrophilic Addition of α-Diazoesters with Ketones for Enantioselective C-N Bond Formation, J. Am. Chem. Soc. 2011, 133, 15268-15271.
125. Yunfei Cai, Xiaohua Liu, Jun Jiang, Weiliang Chen, Lili Lin, Xiaoming Feng,* Catalytic Asymmetric Chloroamination Reaction of α,β-Unsaturated γ-Keto Esters and Chalcones, J. Am. Chem. Soc. 2011, 133, 5636-5639.
126. Ke Shen, Xiaohua Liu, Gang Wang, Lili Lin, and Xiaoming Feng,* Facile and Efficient Enantioselective Hydroxyamination Reaction: Synthesis of 3-Hydroxyamino-2-Oxindoles Using Nitrosoarenes, Angew. Chem. Int. Ed. 2011, 50, 4684-4688.
127. Zhen Wang, Zhigang Yang, Donghui Chen, Xiaohua Liu, Lili Lin, Xiaoming Feng,* Highly Enantioselective Michael Addition of Pyrazolin-5-ones Catalyzed by Chiral N,N′-dioxide-Lanthanide(III) Complex: Metal Directed Reversal of Enantioselectivity, Angew. Chem. Int. Ed. 2011, 50, 4928-4932.
128. Ke Zheng, Chengkai Yin, Xiaohua Liu, Lili Lin, Xiaoming Feng,* Catalytic Asymmetric Addition of Alkyl Enol Ethers to 1,2-Dicarbonyl Compounds: Highly Enantioselective Synthesis of Substituted 3-Alkyl-3-Hydroxyoxindoles, Angew. Chem. Int. Ed. 2011, 50, 2573-2577.
129. Yunfei Cai, Xiaohua Liu, Jun Li, Weiliang Chen, Wentao Wang, Lili Lin, Xiaoming Feng,* Asymmetric Iodoamination of Chalcones and 4-Aryl-4-oxobutenoates Catalyzed by a Complex Based on Scandium (III) and a N,N′-Dioxide Ligand, Chem. Eur. J. 2011, 17, 14916-14921.
130. Wei Li, Jun Wang, Xiaolei Hu, Ke Shen, Wentao Wang, Yangyang Chu, Lili Lin, Xiaohua Liu, Xiaoming Feng,* Catalytic Asymmetric Roskamp Reaction of α-Alkyl-α-diazoesters with Aromatic Aldehydes: Highly Enantioselective Synthesis of α-Alkyl-β-keto Esters, J. Am. Chem. Soc. 2010, 132, 8532-8533.
131. Shunxi Dong, Xiaohua Liu, Xiaohong Chen, Fang Mei, Yulong Zhang, Bo Gao, Lili Lin, Xiaoming Feng,* Chiral Bisguanidine-Catalyzed Inverse-Electron-Demand Hetero-Diels−Alder Reaction of Chalcones with Azlactones, J. Am. Chem. Soc. 2010, 132, 10650-10651.
132. Yunfei Cai, Xiaohua Liu, Yonghai Hui, Jun Jiang, Wentao Wang, Weiliang Chen, Lili Lin, Xiaoming Feng,* Catalytic Asymmetric Bromoamination of Chalcones: Highly Efficient Synthesis of Chiral α-Bromo-β-Amino Ketone Derivatives, Angew. Chem. Int. Ed. 2010, 49, 6160-6164.
133. Zongrui Hou, Jun Wang, Peng He, Jing Wang, Bo Qin, Xiaohua Liu, Lili Lin, Xiaoming Feng,* Highly Enantioselective Insertion of Carbenoids into N-H Bonds Catalyzed by Copper(I) Complexes of Rigid BINOL Derivatives, Angew. Chem. Int. Ed. 2010, 49, 4763-4766.
134. Yonghai Hui, Jun Jiang, Wentao Wang, Weiliang Chen, Yunfei Cai, Lili Lin, Xiaohua Liu, Xiaoming Feng,* Highly Enantioselective Conjugate Addition of Thioglycolate to Enones Using Mild Lanthanum Catalysis: Lower Catalyst Loading and Remarkably Chiral Amplification, Angew. Chem. Int. Ed. 2010, 49, 4290-4293.
135. Mingsheng Xie, Xiaohong Chen, Yin Zhu, Bo Gao, Lili Lin, Xiaohua Liu, Xiaoming Feng,* Asymmetric Three-Component Inverse Electron-Demand Aza-Diels-Alder Reaction: Efficient Synthesis of Ring-Fused Tetrahydroquinolines, Angew. Chem. Int. Ed. 2010, 49, 3799-3802.
136. Ke Shen, Xiaohua Liu, Wentao Wang, Gang Wang, Weidi Cao, Wei Li, Xiaolei Hu, Lili Lin, Xiaoming Feng,* Highly Enantioselective Synthesis of 1,3-Bis(hydroxymethyl)-2-oxindoles from Unprotected Oxindoles and Formalin Using a Chiral Nd(III) Complex, Chem. Sci. 2010, 1, 590-595.
137. Zhipeng Yu, Xiaohua Liu, Lin Zhou, Lili Lin, Xiaoming Feng,* Bifunctional Guanidine via an Amino Amide Skeleton for Asymmetric Michael Reactions of β-Ketoesters with Nitroolefins: A Concise Synthesis of Bicyclic β-Amino Acids, Angew. Chem. Int. Ed. 2009, 48, 5195-5198.
138. Jun Wang, Wentao Wang, Wei Li, Xiaolei Hu, Ke Shen, Cheng Tan, Xiaohua Liu, Xiaoming Feng,* Asymmetric Cyanation of Aldehydes, Ketones, Aldimines, and Ketimines Catalyzed by a Versatile Catalyst Generated from Cinchona Alkaloid, Achiral Substituted 2,2’-Biphenol and Tetraisopropyl Titanate, Chem. Eur. J. 2009, 15, 11642-11659.
139. Xiaohua Liu, Lili Lin, Xiaoming Feng,* Amide-Based Bifunctional Organocatalysts in Asymmetric Reactions, Chem. Commun. 2009, 6145-6158.
140. Ke Zheng, Jian Shi, Xiaohua Liu, Xiaoming Feng,* Asymmetric Carbonyl-Ene Reaction Catalyzed by Chiral N,N′-Dioxide-Nickel(II) Complex: Remarkably Broad Substrate Scope, J. Am. Chem. Soc. 2008, 130, 15770-15771.
141. Jie Liu, Zhigang Yang, Zhen Wang, Fei Wang, Xiaohong Chen, Xiaohua Liu, Xiaoming Feng,* Zhishan Su, Changwei Hu*, Asymmetric Direct Aldol Reaction of Functionalized Ketones Catalyzed by Amine Organocatalysts Based on Bispidine, J. Am. Chem. Soc. 2008, 130, 5654-5655.
142. Lijia Wang, Xiaohua Liu, Zhenhua Dong, Xuan Fu, Xiaoming Feng,* Asymmetric Intramolecular Oxa-Michael Addition of Activated α,β-Unsaturated Ketones Catalyzed by a Chiral N,N′-Dioxide Nickel(II) Complex: Highly Enantioselective Synthesis of Flavanones, Angew. Chem., Int. Ed. 2008, 47, 8670-8673.
143. Xu Yang, Xin Zhou, Lili Lin, Lu Chang, Xiaohua Liu, Xiaoming Feng,* Highly Enantioselective Direct Michael Addition of Nitroalkanes to Nitroolefins Catalyzed by La(OTf)3/N,N′-Dioxide Complexes, Angew. Chem. Int. Ed. 2008, 47, 7079-7081
144. Zhipeng Yu, Xiaohua Liu, Zhenhua Dong, Mingsheng Xie, Xiaoming Feng,* An N,N′-Dioxide/In(OTf)3 Catalyst for the Asymmetric Hetero-Diels-Alder Reaction Between Danishefsky's Dienes and Aldehydes: Application in the Total Synthesis of Triketide, Angew. Chem., Int. Ed. 2008, 47, 1308-1311.
145. Xin Zhou, Xiaohua Liu, Xu Yang, Deju Shang, Junguo Xin, Xiaoming Feng,* Highly Enantioselective Hydrophosphonylation of Aldehydes Catalyzed by Tridentate Schiff Base Aluminum(III) Complexes, Angew. Chem. Int. Ed. 2008, 47, 392-394.
146. Yuehong Wen, Bo Gao, Yingzi Fu, Shunxi Dong, Xiaohua Liu, Xiaoming Feng,* Asymmetric Three-Component Strecker Reactions Catalyzed by trans-4-Hydroxy-L-proline-Derived N,N′-Dioxides, Chem. Eur. J. 2008, 14, 6789-6795.
147. Zongrui Hou, Jun Wang, Xiaohua Liu, Xiaoming Feng,* Highly Enantioselective Strecker Reaction of Ketoimines Catalyzed by an Organocatalyst from (S)-BINOL and L-Prolinamide, Chem. Eur. J. 2008, 14, 4484-4486.
148. Jun Wang, Xiaolei Hu, Jun Jiang, Shaohua Gou, Xiao Huang, Xiaohua Liu, Xiaoming Feng,* Asymmetric Activation of tropos 2,2'-Biphenol with Cinchonine Generating a Remarkably Effective Catalyst for the Asymmetric Strecker Reaction of N-Ts Protected Aldimines and Ketoimines, Angew. Chem. Int. Ed. 2007, 46, 8468-8470.
149. Yuehong Wen, Yan Xiong, Lu Chang, Jinglun Huang, Xiaohua Liu, Xiaoming Feng,* Chiral Bisformamides as Effective Organocatalysts for Asymmetric One-pot, Three-Component Strecker Reaction, J. Org. Chem. 2007, 72, 7715-7719.
150. Xin Zhang, Donghui Chen, Xiaohua Liu, Xiaoming Feng,* Enantioselective Allylation of Ketones Catalyzed by N,N′-Dioxide and Indium(III) Complex, J. Org. Chem. 2007, 72, 5227-5233.
151. Bo Qin, Xiaohua Liu., Jian Shi, Ke Zheng, Haitao Zhao, Xiaoming Feng,* Enantioselective Cyanosilylation of a,a-Dialkoxy Ketones Catalyzed by Proline-Derived in Situ Prepared N-Oxides as Bifunctional Organocatalysts, J. Org. Chem. 2007, 72, 2374-2378.
152. Jinglun Huang, Xiaohua Liu, Yuehong Wen, Bo Qin, Xiaoming Feng,* Enantioselective Strecker Reaction of Phosphinoyl Ketoimines Catalyzed by in situ Prepared Chiral N,N′-Dioxides, J. Org. Chem. 2007, 72, 204-208.
153. Xiao Huang, Jinglun Huang, Yuehong Wen, Xiaoming Feng,* Asymmetric Strecker Reaction of Ketoimines Catalyzed by a Novel Chiral Bifunctional N,N′-Dioxide, Adv. Synth. Catal. 2006, 348, 2579-2584.
154. Yuehong Wen, Xiao Huang, Jinglun Huang, Yan Xiong, Bo Qin, Xiaoming Feng,* Asymmetric Cyanosilylation of Aldehydes Catalyzed by Novel Organocatalysts, Synlett 2005, 2445-2448.
155. Xiaohua Liu, Bo Qin, Bin He, Xiaoming Feng,* Catalytic Asymmetric Cyanosilylation of Ketones by a Chiral Amino Acid Salt，J. Am. Chem. Soc. 2005, 127, 12224-12225.
156. Fu-Xue Chen, Hui Zhou， Xiaohua Liu，Bo Qin, Xiaoming Feng,* Guolin Zhang, Yaozhong Jiang, Enantioselective Cyanosilylation Of Ketones by a Catalytic Double-Activation Method Using Aluminum Complex and N-oxide, Chem. Eur. J. 2004, 10, 4790-4797.
157. Xiaoming Feng, Lianhe Shu, Yian Shi*, Complete Conversion of Racemic Enol Ester Epoxides into Optically Active a-Acyloxy Ketones, J. Am. Chem. Soc. 1999, 121, 11002-11003.
